EEEOR - SULFURYL FLUORIDE
- MSDS: EEEOR
- Manufacturer: MATHESON TRI GAS INC
- Product Name: SULFURYL FLUORIDE
- National Stock Number: -
Product Identification
Product ID:SULFURYL FLUORIDE
MSDS Date:Jan 24 1989
MSDS Number: EEEOR
Kit Part:=== Responsible Party ===
Company Name:MATHESON TRI-GAS, INC.
Address:959 ROUTE 46 EAST
City:PARSIPPANY
State:NJ
ZIP:07054-0624
Country:US
Info Phone Num:(USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
780-471-4036
Chemtrec Ind/Phone:18004249300
Contractor
Telephone: (USA) 973-257-1100, (WHITBY) 905-668-3570, (EDMONTON)
Ingredients
SULFURYL FLUORIDE
CAS: 2699-79-8
Fraction By Weight: >99%
Hazards
Reports of Carcinogenicity:NTP:No IARC:No OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, itching, nausea, vomiting, stomach pain, symptoms of
drunkenness, tingling sensation, lung congestion, convulsions LONG
TERM EXPOSURE: no information on significant adverse effects SKIN
CONTACT: SHORT TERM EXPOSURE: frostbite LONG TERM EXPOSURE: no
information is available EYE CONTACT: SHORT TERM EXPOSURE:
irritation, blurred vision LONG TERM EXPOSURE: no information on
significant adverse effects INGESTION: SHORT TERM EXPOSURE: no
information on significant adverse effects LONG TERM EXPOSURE: no
information is available
Medical Cond Aggravated by Exposure:
First Aid
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: If frostbite or
freezing occur, immediately flush with plenty of lukewarm water
(105-115 F; 41-46 C). DO NOT USE HOT WATER. If warm water is not
available, gently wrap affected parts in blankets. Get immediate
medical attention. EYE CONTACT: Flush eyes with plenty of water for
at least 15 minutes. Then get immediate medical attention.
INGESTION: If a large amount is swallowed, get medical attention.
Fire Fighting
Flash Point:not flammable
Extinguishing Media:carbon dioxide, regular dry chemical Large fires:
Use regular foam or flood with fine water spray.
Fire Fighting Procedures:Do not get water inside container. Move
container from fire area if it can be done without risk. Cool
containers with water spray until well after the fire is out. Stay
away from the ends of tanks. Keep unnecessary people away, isolate
hazard area and deny entry.
Unusual Fire/Explosion Hazard:Negligible fire hazard.
Accidental Release
Spill Release Procedures:Stop leak if possible without personal risk.
Reduce vapors with water spray. Do not get water directly on
material. Do not get water inside container. Keep unnecessary
people away, isolate hazard area and deny entry. Small spills:
Flood with water. Large spills: Dike for later disposal. Stay
upwind and keep out of low areas. Ventilate closed spaces before
entering. Evacuation radius: 150 feet.
Neutralizing Agent:
Handling
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards.
Other Precautions:
Exposure Controls
Respiratory Protection:The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. 50 ppm Any
supplied-air respirator. 125 ppm Any supplied-air respirator. 200
ppm Any self-contained breathing apparatus with a full facepiece.
Any supplied-air respirator with a full facepiece. Escape - Any
air-purifying respirator with a full facepiece and a canister
providing protection against this substance. Any appropriate
escape-type, self-contained breathing apparatus. For Unknown
Concentrations or Immediately Dangerous to Life or Health - Any
supplied-air respirator with full facepiece and operated in a
pressure-demand or other positive-pressure mode in combination with
a separate escape supply. Any self-contained breathing apparatus
with a full facepiece.
Ventilation:Provide local exhaust ventilation system. Ensure compliance
with applicable exposure limits.
Protective Gloves:Wear insulated gloves.
Eye Protection:Wear splash resistant safety goggles with a faceshield.
Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
Other Protective Equipment:For the gas: Protective clothing is not
required. For the liquid: Wear appropriate protective, cold
insulating clothing.
Supplemental Safety and Health
SULFURYL FLUORIDE: 5 ppm (20 mg/m3) OSHA TWA 10 ppm (42 mg/m3) OSHA
STEL (vacated by 58 FR 35338, June 30, 1993) 5 ppm ACGIH TWA 10 ppm
ACGIH STEL 5 ppm (20 mg/m3) NIOSH recommended TWA 10 hour(s) 10 ppm
(40 mg/m3) NIOSH recommended STEL
Chemical Properties
Boiling Pt:-67 F (-55 C)
Melt/Freeze Pt:-215 F (-137 C)
Vapor Pres:>760 mmHg @ 20 C
Vapor Density:3.7
Spec Gravity:1.8 @ -80 C
pH:Not applicable
Evaporation Rate & Reference:Not applicable
Solubility in Water:10% @ 9 C
Appearance and Odor:PHYSICAL STATE:gas COLOR:colorless ODOR:odorless
Corrosion Rate:
Stability
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Minimize contact with material. Avoid
inhalation of material or combustion by-products. Containers may
rupture or explode if exposed to heat.
Hazardous Decomposition Products:Thermal decomposition products: acid
halides, oxides of sulfur Thermal decomposition products: acid
halides, oxides of sulfur
Conditions to Avoid Polymerization:Will not polymerize.
Disposal
Waste Disposal Methods:Dispose in accordance with all applicable
regulations.
Toxicology
Toxicological Information:SULFURYL FLUORIDE: TOXICITY DATA: 991 ppm/4
hour(s) inhalation-rat LC50; 100 mg/kg oral-rat LD50 LOCAL EFFECTS:
Irritant: inhalation, eye ACUTE TOXICITY LEVEL: Toxic: inhalation,
ingestion MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory
disorders REPRODUCTIVE EFFECTS DATA: Available.
Other Information
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ecology
Ecological:Not available
Transport
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Sulfuryl fluoride ID NUMBER: UN2191 HAZARD CLASS OR DIVISION: 2.3
LABELING REQUIREMENTS: Poison gas QUANTITY LIMITATIONS: PASSENGER
AIRCRAFT OR RAILCAR: Forbidden CARGO AIRCRAFT ONLY: 25 kg
Regulatory
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated. SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: No
REACTIVE: No SUDDEN RELEASE: Yes SARA TITLE III SECTION 313 (40
CFR 372.65): SULFURYL FLUORIDE
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4): Not regulated. OSHA PROCESS SAFETY
(29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.